Is there a pressure at which any gas becomes a liquid, or are some gases genuinely impossible to squeeze into liquid at room temperature?
My mental model of gases and liquids has always been that pressure and temperature trade off against each other: cool something enough and it liquefies, or squeeze it enough and it liquefies, and you can get there by either road.
That model predicts that every gas should have some pressure at room temperature where it turns liquid, even if that pressure is absurd.
I went looking for the number for a couple of common gases and could not find one, which makes me think the model is wrong rather than the data missing. Is there a hard limit here, and if so what sets it?
@orbital_ola · 5d ago
The reason behind the limit is worth having, because it makes it stop feeling arbitrary.
A liquid holds together because its molecules attract each other enough to stay in contact while still moving. Heat is molecular motion. Raise the temperature and at some point the molecules are moving fast enough that the attraction between them cannot keep them condensed, no matter how tightly you pack them.
Compressing harder does not help because squeezing does not slow anything down — it just puts fast-moving molecules closer together. You end up with a dense, hot fluid rather than a liquid.
Which is why the critical temperature tracks how strongly molecules attract one another. Water, which hydrogen-bonds strongly, has a critical temperature above 370 Celsius. Helium, which barely attracts anything, is around 5 kelvin. Hydrogen is a small, light, weakly attracting molecule, so it sits near the bottom.
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