For the DNS variant of the error — messages mentioning DNSSEC or a missing key — the failure is a layer below your web server and no amount of web configuration will fix it.
DNSSEC is signed DNS, and if the signatures are broken or a key was rotated without updating the delegation, a validating resolver gets no answer at all. The authority validates, so it sees nothing; a browser using a non-validating resolver may still work, which is why the site looks fine to you.
That mismatch is the tell. If your domain resolves for you and not for the authority, test it against a validating resolver and check the delegation records at your registrar rather than debugging the server.