Attack the daytime, not the night. A west facing top floor room absorbs heat all afternoon into the walls and ceiling, and that mass radiates all night, which is why opening the window at 11pm does so little.
What measurably worked in a similar flat: blackout blind plus a cheap reflective panel in the window from about 1pm, window shut during the hottest part of the day, then windows wide open the moment outside drops below inside. I bought a cheap thermometer for outside the window purely to know when that moment was. Took about 2.5C off my overnight low.